Results and discussion (continued)
Positions and assignments of the absorption and fluorescence
excitation bands of XeF2.
|
State
|
Assignment
|
lex(nm)
|
nex(cm−1)
|
Dnex(cm−1)
|
|
10σg→7σu
|
|
158.00
|
63 291
|
|
|
5πu 3/2→6sR
|
11211
|
145.65
|
68 657
|
−667
|
|
11
|
145.38
|
68 785
|
−539
|
|
1122
|
145.10
|
68 917
|
−407
|
|
1124 or 222
|
144.84
|
69 041
|
−283
|
|
211
|
144.51
|
69 199
|
−125
|
|
0
|
144.25
|
69 324
|
0
|
|
22
|
144.00
|
69 444
|
120
|
|
24 or 11222
|
143.73
|
69 575
|
251
|
|
11211
|
143.42
|
69 725
|
401
|
|
11
|
143.18
|
69 842
|
518
|
|
1122
|
142.93
|
69 964
|
640
|
|
1124 or 12222
|
142.65
|
70 102
|
778
|
|
12211
|
142.37
|
70 240
|
916
|
|
12
|
142.11
|
70 368
|
1044
|
|
1222
|
141.87
|
70 487
|
1163
|
|
1224 or 13222
|
141.62
|
70 611
|
1287
|
|
13211
|
141.32
|
70 761
|
1437
|
|
13
|
141.04
|
70 902
|
1578
|
|
5πu 1/2→6sR
|
12222
|
137.54
|
72 706
|
−1182
|
|
12211
|
137.38
|
72 791
|
−1097
|
|
12
|
137.20
|
72 886
|
−1002
|
|
11222
|
136.55
|
73 233
|
−655
|
|
11211
|
136.40
|
73 314
|
−574
|
|
11
|
136.23
|
73 405
|
−483
|
|
211
|
135.57
|
73 763
|
−125
|
|
0
|
135.34
|
73 888
|
0
|
|
213
|
135.18
|
73 975
|
87
|
|
22
|
135.01
|
74 069
|
181
|
|
11222
|
134.80
|
74 184
|
296
|
|
11211
|
134.69
|
74 245
|
357
|
|
11
|
134.50
|
74 349
|
461
|
|
11213
|
134.17
|
74 532
|
644
|
|
1122
|
133.99
|
74 632
|
744
|
|
12
|
133.65
|
74 822
|
934
|
|
13
|
132.86
|
75 267
|
1379
|
|
3πg→7σu or
4πu→7σu
|
|
125−140
|
|
|
|
5πu 3/2→5dR
|
11211
|
126.96
|
78 765
|
−619
|
|
11
|
126.82
|
78 852
|
−532
|
|
12
|
126.58
|
79 001
|
−383
|
|
222
|
126.33
|
79 158
|
−226
|
|
211
|
126.13
|
79 283
|
−101
|
|
0
|
125.97
|
79 384
|
0
|
|
22
|
125.73
|
79 536
|
152
|
|
11222
|
125.46
|
79 707
|
323
|
|
11211
|
125.28
|
79 821
|
437
|
|
11
|
125.10
|
79 936
|
552
|
|
5πu 3/2→5dσR
|
11
|
124.61
|
80 252
|
−517
|
|
0
|
123.81
|
80 769
|
0
|
|
11
|
122.99
|
81 307
|
538
|
|
12
|
122.16
|
81 860
|
1091
|
|
13
|
121.34
|
82 413
|
1644
|
|
14
|
120.48
|
83 001
|
2232
|
|
5πu 1/2→5dR
|
...
|
119.54
|
83 654
|
−748
|
|
...
|
119.34
|
83 794
|
−608
|
|
11222
|
119.14
|
83 935
|
−467
|
|
11211
|
118.98
|
84 048
|
−354
|
|
11
|
118.84
|
84 147
|
−255
|
|
211
|
118.48
|
84 402
|
0
|
|
...
|
117.96
|
84 774
|
372
|
|
...
|
117.80
|
84 890
|
488
|
|
...
|
117.48
|
85 121
|
719
|
|
5πu 1/2→5dσR
|
11
|
116.96
|
85 499
|
−515
|
|
0
|
116.26
|
86 014
|
0
|
|
11
|
115.58
|
86 520
|
506
|
|
12
|
114.86
|
87 063
|
1049
|
|
13
|
114.18
|
87 581
|
1567
|
|
5πu 3/2→7sR
|
11
|
116.38
|
85 925
|
−401
|
|
0
|
115.84
|
86 326
|
0
|
|
11
|
115.22
|
86 790
|
464
|
|
12
|
114.58
|
87 275
|
949
|
|
13
|
113.94
|
87 765
|
1439
|
|
14
|
113.19
|
88 347
|
2021
|
|
15
|
112.53
|
88 865
|
2539
|
|
10σg→6pσR
|
11
|
115.14
|
86 851
|
−539
|
|
0
|
114.43
|
87 390
|
0
|
|
11
|
113.78
|
87 889
|
499
|
|
12
|
113.13
|
88 394
|
1004
|
|
13
|
112.39
|
88 976
|
1586
|
|
5πu 1/2→7sR
|
0
|
111.06
|
90 041
|
0
|
|
5πu 3/2→6dR
|
11
|
110.76
|
90 285
|
−542
|
|
0
|
110.10
|
90 827
|
0
|
|
11
|
109.61
|
91 233
|
406
|
|
12
|
108.99
|
91 752
|
925
|
|
5πu 3/2→8sR
|
11
|
108.24
|
92 387
|
−1560
|
|
0
|
107.68
|
92 868
|
0
|
|
11
|
107.18
|
93 301
|
2474
|
|
12
|
106.58
|
93 826
|
2999
|
|