Results and discussion (continued)
Positions and assignments of the absorption and fluorescence excitation bands of XeF2. State Assignment lex(nm) nex(cm−1) Dnex(cm−1) 10σg→7σu 158.00 63 291 5πu 3/2→6sR 11211 145.65 68 657 −667 11 145.38 68 785 −539 1122 145.10 68 917 −407 1124 or 222 144.84 69 041 −283 211 144.51 69 199 −125 0 144.25 69 324 0 22 144.00 69 444 120 24 or 11222 143.73 69 575 251 11211 143.42 69 725 401 11 143.18 69 842 518 1122 142.93 69 964 640 1124 or 12222 142.65 70 102 778 12211 142.37 70 240 916 12 142.11 70 368 1044 1222 141.87 70 487 1163 1224 or 13222 141.62 70 611 1287 13211 141.32 70 761 1437 13 141.04 70 902 1578 5πu 1/2→6sR 12222 137.54 72 706 −1182 12211 137.38 72 791 −1097 12 137.20 72 886 −1002 11222 136.55 73 233 −655 11211 136.40 73 314 −574 11 136.23 73 405 −483 211 135.57 73 763 −125 0 135.34 73 888 0 213 135.18 73 975 87 22 135.01 74 069 181 11222 134.80 74 184 296 11211 134.69 74 245 357 11 134.50 74 349 461 11213 134.17 74 532 644 1122 133.99 74 632 744 12 133.65 74 822 934 13 132.86 75 267 1379 3πg→7σu or
4πu→7σu125−140 5πu 3/2→5dR 11211 126.96 78 765 −619 11 126.82 78 852 −532 12 126.58 79 001 −383 222 126.33 79 158 −226 211 126.13 79 283 −101 0 125.97 79 384 0 22 125.73 79 536 152 11222 125.46 79 707 323 11211 125.28 79 821 437 11 125.10 79 936 552 5πu 3/2→5dσR 11 124.61 80 252 −517 0 123.81 80 769 0 11 122.99 81 307 538 12 122.16 81 860 1091 13 121.34 82 413 1644 14 120.48 83 001 2232 5πu 1/2→5dR ... 119.54 83 654 −748 ... 119.34 83 794 −608 11222 119.14 83 935 −467 11211 118.98 84 048 −354 11 118.84 84 147 −255 211 118.48 84 402 0 ... 117.96 84 774 372 ... 117.80 84 890 488 ... 117.48 85 121 719 5πu 1/2→5dσR 11 116.96 85 499 −515 0 116.26 86 014 0 11 115.58 86 520 506 12 114.86 87 063 1049 13 114.18 87 581 1567 5πu 3/2→7sR 11 116.38 85 925 −401 0 115.84 86 326 0 11 115.22 86 790 464 12 114.58 87 275 949 13 113.94 87 765 1439 14 113.19 88 347 2021 15 112.53 88 865 2539 10σg→6pσR 11 115.14 86 851 −539 0 114.43 87 390 0 11 113.78 87 889 499 12 113.13 88 394 1004 13 112.39 88 976 1586 5πu 1/2→7sR 0 111.06 90 041 0 5πu 3/2→6dR 11 110.76 90 285 −542 0 110.10 90 827 0 11 109.61 91 233 406 12 108.99 91 752 925 5πu 3/2→8sR 11 108.24 92 387 −1560 0 107.68 92 868 0 11 107.18 93 301 2474 12 106.58 93 826 2999